@ font-face works with Persian fonts. However, browsers are pretty distorted. Typically, Macs typically require AAT tables in addition to OpenType, and Chrome does not make an Arabic script layout at all. Chrome bug fixed.
http://farsitel.com/fa/ is one site that uses a web font (their "Iranian Sans" are based on DejaVu).
The webfonts.fonts.com monotype contains several Arabic script fonts, subject to similar limitations.
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