It depends on whether you have values in the header (RFC 5322) or in the addresses of the envelope (RFC 5321), and in the latter case, whether you include <> everything between <> (that is, the source route) or just the mailbox.
RFC 5322, RFC 5322 , ! ! ! !. Perl: Mail:: RFC822:: Address.
RFC 5321 4.1.3, 1.2.3.4 "standard-tag:" (, [IPv6:::1]). , " ", < > .
, , SMTP- . (, , , SMTP.)
( , RFC 5336 a.k.a. "UTF8SMTP". , .)