Include the XML file in the project files in Visual Studio, then in the properties window, make sure that the parameter is Build Actionset to Contentand is Copy to Output Directoryset to Copy alwaysor Copy if newer. This will include the file in the XAP output file.
To access this file in code, use:
XDocument doc = XDocument.Load( "path/to/my/file.xml" );
, XDocument, XML .