MFC . , (/) , , . , 18- , . .
, Windows Forms WPF - , lingua franca - C ++ ( Java - ).
Depending on what you want to do and how important the very user-friendly GUI is, MFC may be the only choice, especially if you can afford to buy third-party components and use a functional package or ribbons.
I do not comment on QT / GTK / FLTK or other tools until you tell us more about your project
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