In the near future (5.6.4) MySQL will provide fractional seconds in TIMESTAMP columns, however even fractional seconds are not guaranteed to be unique, although theoretically they are most often unique, especially if you have limited MySQL to a single thread.
You can use the UUID if you need a unique number that is ordered temporarily.
SELECT UUID() gives something like:
45f9b8d6-8f00-11e1-8920-842b2b55ce56
And after a while:
004b721a-8f01-11e1-8920-842b2b55ce56
UUID , , , SUBSTR() CONCAT() :
SELECT CONCAT(SUBSTR(UUID(), 15, 4), '-', SUBSTR(UUID(), 10, 4),
'-', SUBSTR(UUID(), 1, 8))
:
11e1-8f00-45f9b8d6
, , , . UUID() , ( ), ( , auto_increment).
UUID() , PHP microtime() , . (web), , microtime() .