Web @Work is a dual-mode application. This means that if it is installed on a device with MobileIron infrastructure, it uses MobileIron for security and management (AppConnect mode). If this infrastructure is missing, it works offline (not in the AppConnect application), and it is not protected or managed by MobileIron.
If I understand your question correctly, you are creating a site and want to check that it works correctly with Web @Work. You should be able to do this by simply installing the browser application from iTunes and browsing like in any other browser.
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