As I understand it, the changes from .NET 2.0 to 3.5 are mainly focused on adding to the .NET 2.0 library, more like an add-on package, rather than a new version of the framework (so as not to reduce many of the additional features that you get). Thus, I would suggest that you see only a minimal increase in speed, possibly from minor updates to the framework. All of this assumes that you are sticking to winforms and your current code base. As always, changing the code leads to a completely different ball game!
Good luck
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