As others have said, MSDN belongs to the category of sites about which you can say: "Google searches for X better than X searches for X." Notable peers include Wikipedia and StackOverflow.
To simplify the use of Google, Google will allow you to create custom search engines that are not limited to searching only a specific site, but also allow you to set other requirements. For example, if you click my name to see my SO user profile, you will see that I have MSDN and StackOverflow search links in the box in the upper right. I don't have a job yet, but in the end I will have the StackOverflow search setting only to return question pages and exclude user pages or tags.
However, one thing you are missing is that when you use the Microsoft language, you are probably also using Visual Studio. And if so, intellisense hints contain the information you need in 90% of cases. So in this sense it is even better than php because you don’t even need to open a web browser.
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