How to select the first character of a cell and use it to determine what is returned?
Take a look at MySQL "String" and "Control Flow" Functions .
For instance:
SELECT IF( LEFT( myField, 1) = 'a', 1, 0) FROM myTable;
will return 1 for fields starting with 'a' and 0 for all other values
Try reading this article.
Choosing strings where the first n-characters are equal (MySQL)
Also provides an article on mysql regexes
http://www.unixcities.com/mysql/manual_regexp.html