Assuming the cursor is at the beginning of a word, use
gUl
(if the word was lowercase) or
gUllgue
to explicitly create the first letter capital and another lower case register.
Same as you used, instead of w (word motion) you use l (single character movement).
If the cursor is somewhere in the middle of the word, add b (jump to the beginning of the word) to the commands above.
You can map some key to do this if you use it often.
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