Let me break it down and simplify it for readability:
  bytes = """ 00 00 00 90 ff 53 4d 42 72 00 00 00 00 18 53 c8 00 00 00 00 00 00 00 00 00 00 00 00 ff ff ff fe 00 00 00 00 00 6d 00 02 50 43 20 4e 45 54 57 4f 52 4b 20 50 52 4f 47 52 41 4d 20 31 2e 30 00 02 4c 41 4e 4d 41 4e 31 2e 30 00 02 57 69 6e 64 6f 77 73 20 66 6f 72 20 57 6f 72 6b 67 72 6f 75 70 73 20 33 2e 31 61 00 02 4c 4d 31 2e 32 58 30 30 32 00 02 4c 41 4e 4d 41 4e 32 2e 31 00 02 4e 54 20 4c 4d 20 30 2e 31 32 00 02 53 4d 42 20 32 2e 30 30 32 00 """ packet = [chr(int(a, 16)) for a in bytes.split()] 
bytes is a string, """ usually used for Python docstrings, but you can use them in your code to create very long strings (but they kind of suck because you end up with extra spaces in the code.
bytes.split() will be split into empty space and will return a list of the individual parts of the string, separated by a space.
 print bytes.split() ['00', '00', '00', '90', 'ff', '53', '4d', '42', '72', '00', '00', '00', '00', '18', '53', 'c8', '00', '00' ... ]  
So then:
 packet = [chr(int(a, 16)) for a in bytes.split()] 
This is a list comprehension:
- split bytesand get this list as above
- for each element in the list ( ahere), execute on it anint(a,16), which will receive its integer value by converting base-16 to decimal conversion (i.e.FFwill be255).
- Then do chrin this value, which will return you the ASCII value of this byte.
So packet will be a list of bytes in ASCII form.
 print packet ['\x00', '\x00', '\x00', '\x90', '\xff', 'S', 'M', 'B', 'r', '\x00', '\x00', '\x00', '\x00', '\x18', 'S', '\xc8', '\x00', '\x00', '\x00', '\x00', '\x00', '\x00', '\x00', '\x00', '\x00', '\x00', '\x00', '\x00', '\xff', '\xff', '\xff', '\xfe', '\x00', '\x00', '\x00', '\x00', '\x00', 'm', '\x00', '\x02', 'P', 'C', ' ', 'N', 'E', 'T', 'W', 'O', 'R', 'K', ' ', 'P', 'R', 'O', 'G', 'R', 'A', 'M', ' ', '1', '.', '0', '\x00', '\x02', 'L', 'A', 'N', 'M', 'A', 'N', '1', '.', '0', '\x00', '\x02', 'W', 'i', 'n', 'd', 'o', 'w', 's', ' ', 'f', 'o', 'r', ' ', 'W', 'o', 'r', 'k', 'g', 'r', 'o', ... more ]