The web service in Android, like any other computer, requests information through HTTP.
“Web services can convert your application into a web application” (from w3schools.com) means you can use web services to provide a richer and more modern experience. For example, if your application is a text editor, it can check web services for updates, and not force the user to check the website for updates. Another example is writing your own Facebook client that will use multiple web service calls and will depend on Facebook for the content presented to the user.
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