Try this instead:
RewriteRule ^([\w]*)/?$ $1.php?nav=$1 [L]
And yes. Backlinks can be used more than once.
UPDATE
According to your comment:
RewriteEngine On RewriteBase /information/ RewriteRule ^article([0-9]+)/?$ get-article.php?article=$1 [L] RewriteRule ^blog([0-9]+)/?$ get-blog.php?nav=blog&entry=$1 [L] RewriteCond %{REQUEST_URI} /new RewriteRule ^([\w]*)/?$ $1.php?nav=$1 [L]
The last condition and the last rule work fine. Result:
http://example.com/new.php?nav=new
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