You have a relationship going from the delivery method to dr / centers, and not from dr / center to the delivery method.
If you cancel the connection, you not only get rid of the need to have a table with a potentially inconsistent column, you can share delivery methods with several numerous drs and centers. You say that there is a 1 to 1 relationship, but if there is no business rule PREVENTING dr or center from the same delivery method as any other dr or cent, then what you have is actually a relationship " many to one "(many dr / centers can have the same delivery method), even if in practice this is unique.
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