If physical access to the machine / user account is available, there should be no problem obtaining a certificate if it was not protected by a user password during import. The export wizard can be launched from Internet Explorer settings, as shown in the figure. Look at the certificate you need on one of the tabs (usually on the Personal tab). Use the PFX format to export both private and public keys.

Another way to access the Export Wizard is through the MMC snap-in .
[UPDATE] . For completeness, it is not possible to obtain the private key from the signed deployment file, since it contains only the public part of the encryption key. Perhaps in the case of OP, the private key is still there, somewhere in the file system of the development machine (like the .VVK file), although it would be bad practice to store it like that. More information about certificate file types can be found here . I would prefer both private and public keys to be found in the machine certificate store, as described above.
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