To answer your explicit question, yes, it is safe.
To answer a question that you did not know, you had:
in python 2.x: dict.keys() returns a list of keys.
But doing for k in dict iteration over them.
Iteration is faster than creating a list.
in python 3+, explicitly calling dict.keys() not slower because it also returns an iterator.
Most dictionary needs can usually be solved by iterating over items() instead of keys as follows:
for k, v in dict.items():
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