If you mean the key * from your hardware keyboard (on devices that it has), you can capture it using KeyCode.
Here you can find an extensive list of all the keys that you can intercept.
For this:
@Override public boolean onKeyDown(int keyCode, KeyEvent event) { switch (keyCode) { case KeyEvent.KEYCODE_STAR:
EDIT
Responding to your comment, I do not think this is possible. KeyDown / Up events are handled in action. And you will not be active. Check this!
EDIT
Yes, according to this guy you cannot.
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