Nope.
This is a requirement to ask to subscribe to two Google accounts (or two Live IDs or any other accounts) in one browser instance (which may actually be possible using Chrome , but there is NO general case). It is simply not possible today.
However, it is ugly to see this error message on the ACS website. Have you configured the ERROR URL for your relying party in ACS? Although this property is optional, I strongly recommend that customers use it and handle requests correctly. I have not tried your specific scenario, but I believe that ACS will redirect the user to the error URL after configuring it, so you at least know what is going on.
Please configure the error URL for your relying party and let us know if the user will be redirected to your site. Then you can create the correct error message.
UPDATE
If you say that this only happens when you log in to the Azure Management Portal, then this (my spec!) Is almost the same as logging in with WAAD. There have been some changes with GA WAAD. If you follow the actual login flow using Fiddler, you will notice that when the login to the management portal has a slightly different flow, then, for example, logging into Hotmail. If you log in to Hotmail, you simply redirect to login.live.com , you log in and return to Hotmail.
Now, if you check the traffic when navigating through manage.windowsazure.com , you will notice that there is a first redirect to login.microsoftonline.com (this is WAAD being processed!). It then redirects to login.live.com (this is for your Live ID account). My guess is that WAAD from login.microsoftonline.com combines the Live ID ( login.live.com ) for authentication. This is why you are really logged in with WAAD and why your application is not working.
Please do the following experiment to make sure that I am wrong or not:
- Delete all browser cookies.
- Go to Hotmail and log in to your Live ID account.
- Now open a new tab and open your own application that integrates WAAD through ACS
I suspect you can now log in to your application.
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