Run all the automated tests that the system has.
If the system does not have automatic tests or if automatic tests have poor coverage, you need to create more tests, perhaps in combination with manual testing.
It is imperative that you have a 32-bit version installed for comparison. Thus, you can distinguish between old errors and errors that were introduced during porting. This is especially important if the system is not new for you, so you do not know how it should work.
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