Gathering the comments of my and other people into one answer for posterity, your line probably contains non-printable control characters. Try
System.out.println( (int)thisLine.charAt(0) )
to print their numeric code or
my_string.replaceAll("\\p{C}", "?");
"?".
System.out.println( (int)thisLine.charAt(0) ) 65279 , , , . (. # 65279; HTML?).
, (my_string.replaceAll("\\p{C}", "");) @arvind (thisLine = thisLine.trim();) , .
: "" . , , Notepad ++.