Microsoft operating systems use Kerberos authentication, so you cannot directly use your ID + password.
I am on Linux, so I cannot test it directly, but I think you can create a proxy server with fiddler, which can deny authentication for you, and you can use this proxy with python.
Fiddler Composer will automatically answer authentication calls (including the Negotiate protocol that wraps Kerberos) if you check the Authentication checkbox on the Options tab of the menu.
macdrai
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