First, specify the folder in which you will create the solutions.
Then, in VWD 2010 Express, create a new project from the File menu. Select the Windows templates under your preferred language (e.g. C #) and highlight Class Library. Name your class (ie, "Domain") and below that you have options to set the base directory for the solution folder "Create a new solution" and provide the "Solution name" in "Create a directory for the solution."
Then you can use the File → Add ... option to add resources to your solution.
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