ADFS v2.0 only authenticates against AD. If your current authentication method is something else (like SQL Server), then you need a custom STS.
Are these applications all ASP.NET?
If so, they should all be allowed using WIF.
If not, if, for example, Java, you have to protect them with another solution, for example. OpenSSO / Ping Federate and integrates this product with ADFS.
If classic ASP, there are ways to allow ADFS to handle authentication, but authorization is a problem. Roles will be in the claims object, which Classic ASP does not have access to. You can also use C2WTS for this.
Are you looking at authentication or authorization, or both? ADFS provides roles within the claims object, so the existing authorization mechanism in your programs may change.
You can download the balance of ADFS sites.
ADFS can certainly enable SSO on all of your sites. It also potentially allows you to integrate with other sites / organizations and use external credentials (like Facebook) through Azure ACS, if that's what you need to keep in mind in the future.
It also integrates with SharePoint 2010, CRM Dynamics 2010, and Office 365, all of which are included.
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