As a revision of my initial answer, as a result of which a conclusion was drawn, rather than an explanation, I would postulate * that the effect is manifested because you assume a negative bias, which can be used to compensate for the position on the positive curve, when actually minus the values ββthat you use on the negative curve.
First, it would be necessary for the skew measure to be singular and occur on the same curve (see normal curve below) with positive and negative values ββthat allow shifting along the curve.

However, the curve for negative and positive skews is reversed by the tail.
Zero skew is the only value that affects both. So, if you have an element, apply a skew of 20 degrees to it, and then apply a skew of minus 20, you will actually have oblique (positive or negative) values ββof zero, so using a negative bias will work ..
However, if you then apply an additional negative skew, you will have a negatively distorted element, the curve for which is different and not equal to the inverse equivalent position on the positive curve.
20deg = Original element, 20deg on a positive oblique curve
20deg - 20deg = 0, same for positive and negative oblique curve
-40deg = taking current elements 20deg skew, minus 40 deg = 20deg on the negative oblique curve - NOT the equivalent "opposite" point on the positive oblique curve
When using psuedos, skew works because you arent compensating for the positively distorted value with a new distorted amount.
* I'm not a mathematician, so I'm afraid I can only state this as a hypothesis