If you want to group a series in a histogram, you will need to use the Chart.DataBindTable (MSDN) method.
Just add the following code:
Chart1.DataBindTable(IEtable, "Day");
This will result in a chart that looks something like this: 
Here is some dummy code to use as a test:
DataTable table = new DataTable(); table.Columns.Add("Day", typeof(string)); table.Columns.Add("Email", typeof(int)); table.Columns.Add("Calls", typeof(int)); table.Columns.Add("Contacts", typeof(int)); table.Columns.Add("Tasks", typeof(int)); table.Columns.Add("Meetings", typeof(int)); table.Columns.Add("Proposals", typeof(int)); table.Rows.Add("Monday", 1, 3, 3, 4, 5, 5); table.Rows.Add("Tuesday", 1,6,8,2,0,3); table.Rows.Add("Wednesday", 7, 6,3,0,2,1); table.Rows.Add("Thursday", 1,5,5,9,3,1); table.Rows.Add("Friday", 4,7,3,5,2,3);
It is also possible for labels to appear as you describe using ECCTMP, but adding a legend will probably look cleaner.