This will be because your JIT web application is up to 32 bits long, so you cannot load the 64-bit assembly into the workflow.
There are very few reasons why you need to build a web application assembly for a specific bit. Do you need a class library for x64, or can you leave it as AnyCPU?
Also, does IIS work on a 64-bit machine with a 64-bit OS? If either 32 bits, but you cannot load the 64-bit assembly.
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