Try the following:
SELECT port FROM interfaces ORDER BY SUBSTRING_INDEX(port, '/', 1), CAST(SUBSTRING_INDEX(port, '/', -1) AS SIGNED)
Check SQL FIDDLE DEMO
OUTPUT
| PORT | |--------| | Fa0/1 | | Fa0/2 | | Fa0/3 | | Fa0/4 | | Fa0/5 | | Fa0/6 | | Fa0/7 | | Fa0/8 | | Fa0/9 | | Fa0/10 | | Fa0/11 | | Fa0/12 | | Gi0/1 | | Gi0/2 | | Null0 | | Vlan1 |
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