You had to configure several certificates using the server name pointer without knowing it.
If you use this, you get a self-signed certificate:
openssl s_client -showcerts -connect www.minol-fb.de:443
If you use this (with the server name), you will receive the correct certificate:
openssl s_client -showcerts -connect www.minol-fb.de:443 -servername www.minol-fb.de
You will probably act differently with older versions of IE because you are testing them on XP. Unfortunately, IE does not support SNI in Windows XP. Other browsers (with fairly recent versions) do, at least regardless of the version of the OS on which they work.
If you do not need this other host, you can remove this configuration so that you do not rely on SNI at all.
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