The problem is that there are two heroku executables on your system: one in system paths like /usr/local/bin/heroku (provided by Toolbelt), and one in rbenv gaskets because Ruby 2.0.0-dev had a stone "heroku" is installed.
Since the rbenv pad directory usually has a higher priority, it blocks the call from the heroku ever executable executable file provided by Toolbelt.
The solution is to remove any instance of the "heroku" gem and rely solely on Toolbelt to use all the heroes on the command line:
for v in `rbenv whence heroku`; do RBENV_VERSION=$v gem uni heroku -ax; done rbenv rehash which heroku
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